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陶瓷粉體顆粒

2015-2-28 10:13:33      點(diǎn)擊:
所謂粉體顆粒是指在物質(zhì)的本質(zhì)結(jié)構(gòu)不發(fā)生改變的前提下,分散或細(xì)化得到的固態(tài)基本顆粒。
這種基本顆粒;一般是指沒(méi)有堆積、絮聯(lián)結(jié)構(gòu)的最小顆粒即一次顆粒。而粉體隨著顆粒尺寸的減小,表面活性增大,顆粒之間的靜電吸引力、范德華作用、毛細(xì)管作用等較弱的相互作用顯得越來(lái)越重要,而形成二次顆粒、三次顆粒等所謂團(tuán)聚體。如圖4-4所示為粉料中顆粒團(tuán)聚示意圖,可區(qū)分為三個(gè)不同尺寸層次的結(jié)構(gòu):團(tuán)聚體、顆粒疇和初始顆粒。顆粒疇和初始顆粒的區(qū)別通常不考慮,統(tǒng)稱為顆粒。

上圖是粉料中陶瓷顆粒團(tuán)聚示意圖
所以,對(duì)一次顆粒和二次顆粒必須加以區(qū)別和認(rèn)識(shí)。通常認(rèn)為:一次顆粒直接與物質(zhì)的本質(zhì)相聯(lián)系,二次顆粒則往往是作為研究和應(yīng)用工作中的一種對(duì)顆粒的物態(tài)描述指標(biāo)。
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